Your choice (benzoic acid) is

(I changed my mind and I WANT to separate the p-chloroaniline first!)

Let's begin with the separation of benzoic acid.

If you want to make only benzoic acid* water soluble, which aqueous solution will you add?

dilute aqueous HCl
dilute aqueous NaOH
saturated aqueous NaHCO3

Click ADD to add the selected solution to the separatory funnel